Takaluoma Esther M, Oilunkaniemi Raija, Laitinen Risto S
Department of Chemistry, P.O. Box 3000, FI-90014 University of Oulu, Finland.
Acta Crystallogr Sect E Struct Rep Online. 2014 Sep 3;70(Pt 10):m343-4. doi: 10.1107/S1600536814019503. eCollection 2014 Oct 1.
The dinuclear title compound, [PdCl{Se[(C5H5)Fe(C5H3)2CH2N(CH3)2]}]2 was obtained by the reaction of [PdCl2(NCPh)2] with 2-[(N,N'-di-methyl-amino)-meth-yl]ferro-cene-seleno-late and the crystals for the structure determination were grown from a mixture of THF and n-hexane. Both Pd(II) atoms are coordinated by the bridging Se atoms and by the amino N atoms of the bidentate 2-[(N,N'-di-methyl-amino)-meth-yl]ferrocene-seleno-late ligand, as well as by Cl atoms, and show a distorted square-planar coordination. The angle between the Pd-Se-Se planes of the two Pd atoms is 149.31 (3)°. Weak Cl⋯H hydrogen bonds link the binuclear complexes into a three-dimensional network.
双核标题化合物[PdCl{Se[(C5H5)Fe(C5H3)2CH2N(CH3)2]}]2是通过[PdCl2(NCPh)2]与2-[(N,N'-二甲基氨基)-甲基]二茂铁硒酸盐反应得到的，用于结构测定的晶体是从四氢呋喃和正己烷的混合物中生长出来的。两个钯(II)原子均由桥连的硒原子、双齿2-[(N,N'-二甲基氨基)-甲基]二茂铁硒酸盐配体的氨基氮原子以及氯原子配位，并呈现出扭曲的平面正方形配位。两个钯原子的Pd-Se-Se平面之间的夹角为149.31 (3)°。弱的Cl⋯H氢键将双核配合物连接成三维网络。
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