Anzaldo Bertin, Gutiérrez Pérez René, Hernández Téllez Guadalupe, Mendoza Ángel, Moreno Morales Gloria E
Lab. Síntesis de Complejos, Fac. Cs. Quím.-BUAP, Ciudad Universitaria, PO Box, 72592 Puebla, Mexico.
IUCrdata. 2024 Jun 16;9(Pt 7):x240555. doi: 10.1107/S2414314624005558. eCollection 2024 Jul.
The Pd complex bis-{()-(-)--[(biphenyl-2-yl)methyl-idene]1-(4-meth-oxy-phen-yl)ethanamine-κ}di-chlorido-palladium(II), [PdCl(CHNO)], crystallizes in the monoclinic Sohncke space group 2 with a single mol-ecule in the asymmetric unit. The coordination environment around the palladium is slightly distorted square planar. The N-Pd-Cl bond angles are 91.85 (19), 88.10 (17), 89.96 (18), and 90.0 (2)°, while the Pd-Cl and Pd-N bond lengths are 2.310 (2) and 2.315 (2) Å and 2.015 (2) and 2.022 (6) Å, respectively. The crystal structure features inter-molecular N-H⋯Cl and intramolecular C-H⋯Pd inter-actions, which lead to the formation of a supramolecular framework structure.
钯配合物双-{()-(-)--[(联苯-2-基)亚甲基]1-(4-甲氧基苯基)乙胺-κ}二氯钯(II)，[PdCl(CHNO)]，以单斜 Sohncke 空间群 2 结晶，不对称单元中有一个单分子。钯周围的配位环境略呈扭曲的平面正方形。N-Pd-Cl 键角分别为 91.85 (19)、88.10 (17)、89.96 (18) 和 90.0 (2)°，而 Pd-Cl 和 Pd-N 键长分别为 2.310 (2) 和 2.315 (2) Å 以及 2.015 (2) 和 2.022 (6) Å。晶体结构具有分子间 N-H⋯Cl 和分子内 C-H⋯Pd 相互作用，这导致形成超分子框架结构。
