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(吡啶-2-基亚甲基)(三苯基甲基)胺的晶体结构

Crystal structure of (pyridin-2-yl-methyl-idene)(tri-phenyl-meth-yl)amine.

作者信息

Theppitak Chatphorn, Meesangkaew Manlika, Chanthee Songwuit, Sriprang Nimit, Chainok Kittipong

机构信息

Department of Chemistry, Faculty of Science, Naresuan University, Mueang, Phitsanulok 65000, Thailand.

Department of Physics, Faculty of Science and Technology, Thammasat University, Khlong Luang, Pathum Thani 12120, Thailand.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2014 Sep 6;70(Pt 10):o1094-5. doi: 10.1107/S160053681401959X. eCollection 2014 Oct 1.

Abstract

The title Schiff base compound, C25H20N2, crystallizes with two independent mol-ecules (A and B) in the asymmetric unit. In both mol-ecules, the imine group is approximately coplanar with the pyridine ring, with N-C-C-N torsion angles of 170.1 (3) and -172.0 (3) Å. In the crystal, A and B dimers are linked by pairs of C-H⋯π inter-actions and further C-H⋯π bonds link the dimers into a three-dimensional network.

摘要

席夫碱化合物C25H20N2在不对称单元中与两个独立分子(A和B)一起结晶。在这两个分子中,亚胺基团与吡啶环大致共面,N-C-C-N扭转角分别为170.1(3)和-172.0(3)°。在晶体中,A和B二聚体通过C-H⋯π相互作用对相连,并且进一步的C-H⋯π键将二聚体连接成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e42a/4257176/930e8ad1258b/e-70-o1094-fig1.jpg

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