氯代-{4,5-二甲氧基-2-[(2,3-η)-2-丙烯-1-基]苯基-κC(1)}(哌啶-κN)铂(II)乙醇单溶剂合物的晶体结构
Crystal structure of chlorido-{4,5-dimeth-oxy-2-[(2,3-η)-2-prop-2-en-1-yl]phenyl-κC (1)}(piperidine-κN)platinum(II) ethanol monosolvate.
作者信息
Mangwala Kimpende Peter, Thi Da Tran, Nguyen Huu Dinh, Van Meervelt Luc
机构信息
Chemistry Department, University of Kinshasa, Kinshasa XI BP 190, D.R. Congo.
Chemistry Department, Hanoi National University of Education, 136 - Xuan Thuy - Cau Giay, Hanoi, Vietnam.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2014 Oct 31;70(Pt 11):435-7. doi: 10.1107/S1600536814023575. eCollection 2014 Nov 1.
In the title compound, [Pt(C11H13O2)Cl(C5H11N)]·C2H5OH, the Pt(II) cation is penta-coordinated in a distorted square-planar geometry. In the crystal, inversion dimers showing C-H⋯Cl and C-H⋯π inter-actions are further stacked in columns along the a axis via C-H⋯π inter-actions. The ethanol solvate mol-ecule inter-acts with neighbouring meth-oxy groups of methyl-eugenol through O-H⋯O hydrogen bonds.
在标题化合物[Pt(C₁₁H₁₃O₂)Cl(C₅H₁₁N)]·C₂H₅OH中，Pt(II)阳离子以扭曲的平面正方形几何构型进行五配位。在晶体中，呈现C-H⋯Cl和C-H⋯π相互作用的反演二聚体通过C-H⋯π相互作用进一步沿a轴堆积成列。乙醇溶剂化物分子通过O-H⋯O氢键与甲基丁香酚的相邻甲氧基相互作用。
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