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对苯二甲酸双-{2-[双-(2-羟乙基)氨基]-乙醇-κ(3)O,N,O'}锌的晶体结构

Crystal structure of bis-{2-[bis-(2-hy-droxy-eth-yl)amino]-ethanol-κ(3) O,N,O'}zinc terephthalate.

作者信息

Li Ya-Ping, Zang Hu, Sun Dajun, Ming Julia, Su Guan-Fang

机构信息

Department of Ophthalmology, The Second Hospital of Jilin University, 218 Ziqiang Street, Changchun 130041, People's Republic of China.

Department of Orthopedics, The China-Japan Union Hospital of Jilin University Changchun, Changchun 130033, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2014 Oct 11;70(Pt 11):m361-2. doi: 10.1107/S1600536814021771. eCollection 2014 Nov 1.

DOI:10.1107/S1600536814021771
PMID:25484775
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4257296/
Abstract

In the title salt, Zn(C6H15NO3)2, the Zn(II) cation, located on a centre of inversion, is coordinated by four O atoms and two N atoms from two tridentate 2-[bis-(2-hy-droxy-eth-yl)amino]-ethanol (BHEA) ligands, giving rise to a slightly distorted octa-hedral geometry. The terephthalate dianion, located about a centre of inversion, is not coordinated to Zn(II) but is connected through O-H⋯O contacts with Zn(BHEA)2 cations, leading to a three-dimensional crystal structure.

摘要

在标题盐Zn(C₆H₁₅NO₃)₂中，位于对称中心的Zn(II)阳离子由来自两个三齿2-[双-(2-羟乙基)氨基]-乙醇(BHEA)配体的四个O原子和两个N原子配位，形成略微扭曲的八面体几何构型。位于对称中心的对苯二甲酸二阴离子不与Zn(II)配位，而是通过O—H⋯O接触与Zn(BHEA)₂阳离子相连，形成三维晶体结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f49b/4257296/1ccbaeb5915b/e-70-0m361-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f49b/4257296/cfbfb1158304/e-70-0m361-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f49b/4257296/1ccbaeb5915b/e-70-0m361-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f49b/4257296/cfbfb1158304/e-70-0m361-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f49b/4257296/1ccbaeb5915b/e-70-0m361-fig2.jpg

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