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毛细管电泳法分离与分析三嗪类除草剂残留

Separation and analysis of triazine herbcide residues by capillary electrophoresis.

作者信息

Elbashir Abdalla A, Aboul-Enein Hassan Y

机构信息

Chemistry Department, Faculty of Science, University of Khartoum, Khartoum, 11115, Sudan.

Pharmaceutical and Medicinal Chemistry Department, Pharmaceutical and Drug Industries Research Division, National Research Centre, Dokki, Cairo, 12311, Egypt.

出版信息

Biomed Chromatogr. 2015 Jun;29(6):835-42. doi: 10.1002/bmc.3381. Epub 2014 Dec 16.

DOI:10.1002/bmc.3381
PMID:25515940
Abstract

Triazines are widely used in agriculture around the world as selective pre- and post-emergence herbicides for the control of broad leaf and grassy weeds. With high toxicity and persistence, triazines can contaminate the environment and crops, so the development of rapid and sensitive methods for the determination of different triazines is necessary. Capillary electrophoresis comprises a group of techniques used to separate chemical mixtures. Analytical separation is based on different electrophoretic mobilities. This review focuses on the analysis of triazine herbicides with different modes of capillary electrophoresis, including capillary zone electrophoresis, micellar electrokinetic capillary electrophoresis, capillary electrochromatography and nonaqueous capillary electrophoresis. Determinations of triazines in various matrices such as surface water, groundwater, vegetables, soil and grains are emphasized.

摘要

三嗪类化合物作为选择性苗前和苗后除草剂,在世界各地广泛用于农业,以防治阔叶杂草和禾本科杂草。由于具有高毒性和持久性,三嗪类化合物会污染环境和农作物,因此开发快速灵敏的方法来测定不同的三嗪类化合物很有必要。毛细管电泳是用于分离化学混合物的一组技术。分析分离基于不同的电泳迁移率。本文综述聚焦于采用不同模式的毛细管电泳分析三嗪类除草剂,包括毛细管区带电泳、胶束电动毛细管电泳、毛细管电色谱和非水毛细管电泳。重点介绍了在地表水、地下水、蔬菜、土壤和谷物等各种基质中三嗪类化合物的测定。

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