Guo Zhiyong, Yan Dan, Wang Hailong, Tesfagaber Daniel, Li Xinle, Chen Yusheng, Huang Wenyu, Chen Banglin
Department of Chemistry, University of Texas at San Antonio , San Antonio, Texas 78249-0698, United States.
Inorg Chem. 2015 Jan 5;54(1):200-4. doi: 10.1021/ic502116k. Epub 2014 Dec 17.
A new porphyrin-based microporous MOF, {Mn(II)0.5[Mn(II)4Cl(Mn(III)Cl-ttzpp)2(H2O)4]}·(DEF)20·(CH3OH)18·(H2O)12 (UTSA-57), has been constructed from {5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrinato} manganese(III) chloride as the metalloligand. The MOF adopts the rare scu topology with one-dimensional square nanotube-like channels of about 20 Å. UTSA-57a exhibits permanent porosity and displays moderately high performance for C2H2/CH4 separation at room temperature.
一种基于卟啉的新型微孔金属有机框架材料{Mn(II)0.5[Mn(II)4Cl(Mn(III)Cl-ttzpp)2(H2O)4]}·(DEF)20·(CH3OH)18·(H2O)12（UTSA-57），是由氯化{5,10,15,20-四[4-(2,3,4,5-四唑基)苯基]卟啉}锰(III)作为金属配体构建而成。该金属有机框架材料采用罕见的scu拓扑结构，具有约20 Å的一维方形纳米管状通道。UTSA-57a表现出永久孔隙率，并在室温下对C2H2/CH4分离显示出中等高性能。
