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精准调控并构筑基于苝二酰亚胺-四氰基对苯醌(PDI-TCNQ)共晶的不同纳米和微米结构以获得具有不同光电性能的共晶。

Precisely Tailoring the Stoichiometric Stacking of Perylene-TCNQ Co-Crystals towards Different Nano and Microstructures with Varied Optoelectronic Performances.

机构信息

Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Science, Beijing, 100190, China; University of Chinese Academy of Science, Beijing, 100049, China.

出版信息

Small. 2015 May 13;11(18):2150-6. doi: 10.1002/smll.201402330. Epub 2014 Dec 17.

Abstract

Organic charge-transfer co-crystals with varied donor-acceptor stoichiometric ratios and molecular packing structures are controllably prepared with the morphology of nanowires or microblocks. They have distinct charge transport behavior and photoresponsivity. These interesting results pave the way for rational design and preparation of co-crystals with desired functions.

摘要

具有不同给体-受体计量比和分子堆积结构的有机电荷转移共晶通过控制纳米线或微块的形态可控地制备。它们具有独特的电荷输运行为和光响应性。这些有趣的结果为具有预期功能的共晶的合理设计和制备铺平了道路。

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