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精准调控并构筑基于苝二酰亚胺-四氰基对苯醌（PDI-TCNQ）共晶的不同纳米和微米结构以获得具有不同光电性能的共晶。

Precisely Tailoring the Stoichiometric Stacking of Perylene-TCNQ Co-Crystals towards Different Nano and Microstructures with Varied Optoelectronic Performances.

机构信息

Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Science, Beijing, 100190, China; University of Chinese Academy of Science, Beijing, 100049, China.

出版信息

Small. 2015 May 13;11(18):2150-6. doi: 10.1002/smll.201402330. Epub 2014 Dec 17.

DOI:10.1002/smll.201402330
PMID:25522331
Abstract

Organic charge-transfer co-crystals with varied donor-acceptor stoichiometric ratios and molecular packing structures are controllably prepared with the morphology of nanowires or microblocks. They have distinct charge transport behavior and photoresponsivity. These interesting results pave the way for rational design and preparation of co-crystals with desired functions.

摘要

具有不同给体-受体计量比和分子堆积结构的有机电荷转移共晶通过控制纳米线或微块的形态可控地制备。它们具有独特的电荷输运行为和光响应性。这些有趣的结果为具有预期功能的共晶的合理设计和制备铺平了道路。

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引用本文的文献

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Front Chem. 2021 Dec 9;9:764628. doi: 10.3389/fchem.2021.764628. eCollection 2021.
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Molecular insertion regulates the donor-acceptor interactions in cocrystals for the design of piezochromic luminescent materials.分子插入调节共晶体中的供体-受体相互作用以用于压致变色发光材料的设计。
Nat Commun. 2021 Jul 2;12(1):4084. doi: 10.1038/s41467-021-24381-5.