Department of Chemistry & Biochemistry, The Florida State University , Tallahassee, Florida 32306-4390, United States.
ACS Appl Mater Interfaces. 2015 Jan 14;7(1):895-901. doi: 10.1021/am5074694. Epub 2014 Dec 19.
Iron oxide nanoparticles of diameter ca. 12 nm were dispersed into polyelectrolyte complexes made from poly(styrenesulfonate) and poly(diallyldimethylammonium). These nanocomposites were plasticized with salt water and extruded into dense, tough fibers. Magnetometry of these composites showed they retained the superparamagnetic properties of their constituent nanoparticles with saturation magnetization that scaled with the loading of nanoparticles. Their superparamagnetic response allowed the composites to be heated remotely by radiofrequency fields. While the modulus of fibers was unaffected by the presence of nanoparticles the toughness and tensile strength increased significantly.
直径约 12nm 的氧化铁纳米颗粒分散在由聚苯乙烯磺酸盐和聚二烯丙基二甲基氯化铵制成的聚电解质复合物中。这些纳米复合材料用盐水增塑,并挤出成致密、坚韧的纤维。这些复合材料的磁测量表明,它们保留了组成纳米颗粒的超顺磁性,饱和磁化强度与纳米颗粒的负载成正比。它们的超顺磁响应允许复合材料通过射频场远程加热。虽然纤维的模量不受纳米颗粒存在的影响,但韧性和拉伸强度显著增加。