Thomas Morgan L, Yamanaka Keisuke, Ohta Toshiaki, Byon Hye Ryung
Byon Initiative Research Unit, RIKEN, Wako-shi, Saitama 351-0198, Japan.
Chem Commun (Camb). 2015 Mar 7;51(19):3977-80. doi: 10.1039/c4cc08815h.
A perfluorinated alkyl chain grafted to carbon nanotubes is employed in the lithium-oxygen (Li-O2) cell. We demonstrate a highly localized Li-O2 electrochemical reaction in close proximity to the perfluorinated moiety owing to its high O2 affinity. This hydrophobic modification can provide an enhancement in capacity for a very thin microbattery system.
一种接枝到碳纳米管上的全氟烷基链被用于锂氧（Li-O₂）电池中。由于其对氧气的高亲和力，我们证明了在靠近全氟部分的位置发生了高度局部化的Li-O₂电化学反应。这种疏水改性可以提高非常薄的微电池系统的容量。
