Elango Ganesh, Roopan Selvaraj Mohana
Chemistry Research Laboratory, Organic Chemistry Division, School of Advanced Sciences, VIT University, Vellore 632 014, Tamilnadu, India.
Chemistry Research Laboratory, Organic Chemistry Division, School of Advanced Sciences, VIT University, Vellore 632 014, Tamilnadu, India.
Spectrochim Acta A Mol Biomol Spectrosc. 2015 Mar 15;139:367-73. doi: 10.1016/j.saa.2014.12.066. Epub 2014 Dec 25.
Most of researcher focused their research towards synthesize of nanoparticles by the method of applied chemical method which was one of the costliest method. We have focused cheapest and simplest method for the synthesizing of lead nanoparticles (Pb-NPs) using cocos nucifera L extract. The methanolic extract of cocos nucifera L was efficiently used as a reducing agent for synthesizing Pb-NPs. On treatment of lead acetate with cocos nucifera coir extracts, stable Pb-NPs were formed. The synthesized Pb-NPs were further confirmed by UV-visible spectroscopy, X-ray diffraction (XRD), Transmission electron microscope (TEM) and Energy Dispersive (EDAX) analysis. The secondary metabolites present in methanolic extract which can mainly act as a reducing and capping agents for the formation of Pb-NPs were identified by GC-MS. Anti-microbial activity for Pb-NPs against four pathogenic strain's such as Staphylococcus aureus, Escheria coli, Staphylococcus epidermis and Bacillus subtilis. Result states that Pb-NPs size was 47 nm and also shows good activity against S. aureus. Further we report on photocatalytic absorption of malachite green dye processed in short UV wavelength at 254 nm. UV spectral analysis showed peak absorbance at 613 nm with special reference to the excitation of surfaces plasmon vibration by Pb-NPs.
大多数研究人员将他们的研究重点放在通过应用化学方法合成纳米颗粒上,而这是成本最高的方法之一。我们专注于使用椰子(Cocos nucifera L)提取物合成铅纳米颗粒(Pb-NPs)的最便宜且最简单的方法。椰子(Cocos nucifera L)的甲醇提取物被有效地用作合成Pb-NPs的还原剂。用椰子壳提取物处理醋酸铅时,形成了稳定的Pb-NPs。通过紫外可见光谱、X射线衍射(XRD)、透射电子显微镜(TEM)和能量色散(EDAX)分析进一步证实了合成的Pb-NPs。通过气相色谱-质谱联用(GC-MS)鉴定了甲醇提取物中存在的次生代谢物,这些次生代谢物主要可作为形成Pb-NPs的还原剂和封端剂。研究了Pb-NPs对金黄色葡萄球菌、大肠杆菌、表皮葡萄球菌和枯草芽孢杆菌这四种致病菌株的抗菌活性。结果表明,Pb-NPs的尺寸为47nm,并且对金黄色葡萄球菌也表现出良好的活性。此外,我们报道了在254nm的短紫外波长下处理孔雀石绿染料的光催化吸收情况。紫外光谱分析显示在613nm处有峰值吸光度,特别提到了Pb-NPs对表面等离子体振动的激发。