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超声波能量辅助批式染色竹纤维素纤维用活性染料。

Batchwise dyeing of bamboo cellulose fabric with reactive dye using ultrasonic energy.

机构信息

Department of Textile Engineering, Mehran University of Engineering and Technology, Jamshoro 76060, Pakistan.

Department of Textile Engineering, Mehran University of Engineering and Technology, Jamshoro 76060, Pakistan.

出版信息

Ultrason Sonochem. 2015 May;24:178-83. doi: 10.1016/j.ultsonch.2014.12.016. Epub 2015 Jan 3.

Abstract

Bamboo is a regenerated cellulose fiber usually dyed with reactive dyes. This paper presents results of the batchwise dyeing of bamboo fabric with reactive dyes by ultrasonic (US) and conventional (CN) dyeing methods. The study was focused at comparing the two methods for dyeing results, chemicals, temperature and time, and effluent quality. Two widely used dyes, CI Reactive Black 5 (bis-sulphatoethylsulphone) and CI Reactive Red 147 (difluorochloropyrimidine) were used in the study. The US dyeing method produced around 5-6% higher color yield (K/S) in comparison to the CN dyeing method. A significant savings in terms of fixation temperature (10°C) and time (15 min), and amounts of salt (10 g/L) and alkali (0.5-1% on mass of fiber) was realized. Moreover, the dyeing effluent showed considerable reductions in the total dissolved solids content (minimum around 29%) and in the chemical oxygen demand (minimum around 13%) for the US dyebath in comparison to the CN dyebath. The analysis of colorfastness tests demonstrated similar results by US and CN dyeing methods. A microscopic examination on the field emission scanning electron microscope revealed that the US energy did not alter the surface morphology of the bamboo fibers. It was concluded that the US dyeing of bamboo fabric produces better dyeing results and is a more economical and environmentally sustainable method as compared to CN dyeing method.

摘要

竹纤维通常用活性染料进行染色,是一种再生纤维素纤维。本文介绍了用超声(US)和常规(CN)染色方法分批对竹纤维织物进行活性染料染色的结果。研究重点比较了两种方法的染色效果、化学品、温度和时间以及废水质量。本研究使用了两种广泛使用的染料,CI 活性黑 5(双硫酸乙酯砜)和 CI 活性红 147(二氟氯嘧啶)。与 CN 染色方法相比,US 染色方法的颜色得率(K/S)高约 5-6%。在固定温度(10°C)和时间(15 分钟)、盐(10 g/L)和碱(纤维质量的 0.5-1%)的用量方面,实现了显著节省。此外,与 CN 染浴相比,US 染浴的染色废水的总溶解固体含量(最低约 29%)和化学需氧量(最低约 13%)有相当大的降低。色牢度测试的分析表明,US 和 CN 染色方法的结果相似。场发射扫描电子显微镜的微观检查表明,US 能量没有改变竹纤维的表面形态。得出的结论是,与 CN 染色方法相比,US 对竹纤维织物的染色可获得更好的染色效果,并且是一种更经济和环境可持续的方法。

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