Xu W Y, Wu D
a State Key Laboratory of Pollution Control and Resource Reuse , Tongji University , Shanghai 200092 , People's Republic of China.
Environ Technol. 2015 Jul-Aug;36(13-16):1731-44. doi: 10.1080/09593330.2015.1008584. Epub 2015 Feb 16.
Bio-oils were produced from pyrolysis of sewage sludge in a horizontal tubular furnace under the anoxic or anaerobic conditions, by varying operating parameters and moisture content (MC) of the feedstock. Physicochemical properties of the obtained bio-oil (such as density, acid value, kinematical viscosity, high heating value and flash point) were analysed and compared with Chinese fuel standards. Tend, RT and β were found critical to control the yield and physico-chemical properties of bio-oil products. The relative importance of various parameters such as Tend, RT, β and MC was determined and the optimum values for the lowest kinematic viscosity and acid value and the highest yield of the bio-oil were achieved using the orthogonal matrix method. The parameters 550°C, 45 min, 5°C min(-1) and MC of 10% were found effective in producing the bio-oils with most of the desirable physico-chemical properties and yield. Benefit analysis was conducted to further optimize the operating parameters, considering pyrolysis treatment, comprehensive utilization of the pyrolysis products and final disposal of sewage sludge; the results showed the best economy of the pyrolysis parameters 450°C, 75 min, 3°C min(-1) and MC of 10%. The char obtained under this condition may serve as a microporous liquid adsorbent, while the bio-oil may serve as a low grade fuel oil after upgrading it with conventional fuel oil and deacidification. Pyrolysis products may become economically competitive in addition to being environment friendly.
在水平管式炉中,通过改变操作参数和原料的含水量(MC),在缺氧或厌氧条件下对污水污泥进行热解以生产生物油。分析了所得生物油的物理化学性质(如密度、酸值、运动粘度、高热值和闪点),并与中国燃料标准进行了比较。发现热解终温(Tend)、停留时间(RT)和升温速率(β)对控制生物油产品的产率和物理化学性质至关重要。确定了热解终温(Tend)、停留时间(RT)、升温速率(β)和含水量(MC)等各种参数的相对重要性,并使用正交矩阵法获得了最低运动粘度、最低酸值和最高生物油产率的最佳值。发现550°C、45分钟、5°C·min⁻¹和10%的含水量这些参数能有效生产出具有大部分理想物理化学性质和产率的生物油。进行了效益分析以进一步优化操作参数,同时考虑热解处理、热解产物的综合利用和污水污泥的最终处置;结果表明热解参数450°C、75分钟、3°C·min⁻¹和10%的含水量具有最佳经济性。在此条件下获得的焦炭可作为微孔液体吸附剂,而生物油在用常规燃料油提质和脱酸后可作为低等级燃料油。热解产物除了环境友好外,还可能具有经济竞争力。