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用于生物油生产的污水污泥热解的技术与经济评估。

A technical and economic evaluation of the pyrolysis of sewage sludge for the production of bio-oil.

作者信息

Kim Y, Parker W

机构信息

Department of Civil Engineering, University of Waterloo, Waterloo, Canada.

出版信息

Bioresour Technol. 2008 Mar;99(5):1409-16. doi: 10.1016/j.biortech.2007.01.056. Epub 2007 Mar 26.

Abstract

Pyrolysis to produce bio-oil from sewage sludge is a promising way, to not only improve the economical value, but also to reduce pollutants associated with sludge. The aim of this study was to evaluate the production of oil from primary, waste activated and digested sludges. The pyrolysis was performed in a laboratory-scale horizontal batch reactor. The operating temperature ranged from 250 degrees C to 500 degrees C, while a gas phase residence time of 20 min was maintained with 50 ml/min of nitrogen gas as a purge flow. The maximum oil yield was achieved with primary sludge at 500 degrees C. Temperature and volatile solids were the most important factors affecting the yield of oil and char, however, sludge type also affected both results. Pre-treatment of sludge with either acids, a base or a catalyst (zeolite) did not improve the quantity of oil produced. The economic values of the oil produced from primary, TWAS, and digested sludges were estimated as 9.9, 5.6, and 6.9 cent/kg-ds when the value of oil is 32 cent/kg-oil.

摘要

通过热解从污水污泥中生产生物油是一种很有前景的方法,不仅可以提高经济价值,还能减少与污泥相关的污染物。本研究的目的是评估从原生污泥、废弃活性污泥和消化污泥中生产油的情况。热解在实验室规模的卧式间歇反应器中进行。操作温度范围为250℃至500℃,同时以50毫升/分钟的氮气作为吹扫气流,保持气相停留时间为20分钟。原生污泥在500℃时获得了最高的油产量。温度和挥发性固体是影响油和焦炭产量的最重要因素,然而,污泥类型也会影响这两个结果。用酸、碱或催化剂(沸石)对污泥进行预处理并没有提高产油量。当油的价值为32美分/千克油时,原生污泥、TWAS污泥和消化污泥所产油的经济价值估计分别为9.9、5.6和6.9美分/千克干固体。

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