乙烯和氢气驱动的 Rhodathiaborane 反应循环：[(H)2(PPh3)RhSB8H7(PPh3)]和[(η(2)-C2H4)(PPh3)RhSB8H7(PPh3)]的合成与表征。
Rhodathiaborane reaction cycles driven by C2H4 and H2: synthesis and characterization of [(H)2(PPh3)RhSB8H7(PPh3)] and [(η(2)-C2H4)(PPh3)RhSB8H7(PPh3)].
机构信息
ISQCH, Universidad de Zaragoza-CSIC, C/Pedro Cerbuna 12, 50009 Zaragoza, Spain.
出版信息
Dalton Trans. 2015 Mar 21;44(11):5041-4. doi: 10.1039/c4dt03677h.
PMID:25611554
Abstract
New 10-vertex rhodathiaboranes are reported to exhibit reversible reaction chemistry leading to the formation of stoichiometric cycles driven by oxidation/reduction chemistry of the polyhedral boron-based clusters with ethelyne and dihydrogen.
摘要
新的 10 顶点铼硼烷被报道表现出可逆反应化学，导致在多面体硼基簇的氧化/还原化学的驱动下，通过乙烯和氢气的反应形成化学计量的循环。
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