Sun Hezhi, Jin Zhe, Quan Hong, Sun Cuirong, Pan Yuanjiang
Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, China.
Org Biomol Chem. 2015 Mar 7;13(9):2561-5. doi: 10.1039/c4ob02355b.
The benzylsilver cation which emerges from the collisional dissociation of silver(I)-N-benzylbenzamide complexes was characterized by deuterium-labeling experiments, theoretical calculations, breakdown curves and substituent effects. The nucleophilic attack of the carbonyl oxygen on an α-hydrogen results in the generation of the benzylsilver cation, which is competitive to the AgH loss with the α-hydrogen.
通过氘标记实验、理论计算、裂解曲线和取代基效应，对银（I）-N-苄基苯甲酰胺配合物碰撞解离产生的苄基银阳离子进行了表征。羰基氧对α-氢的亲核进攻导致苄基银阳离子的生成，这与α-氢的AgH损失存在竞争关系。
