Schröter Christian, Choi Chang Min, Schultz Thomas
Ulsan National Institute of Science and Technology (UNIST) , 50 UNIST-gil, Ulsan 689-798, Republic of Korea.
J Phys Chem A. 2015 Feb 26;119(8):1309-14. doi: 10.1021/jp511579z. Epub 2015 Feb 17.
We use correlated rotational alignment spectroscopy to reveal atomic scrambling in transient ionic states of butadiene. Investigating a natural sample, we assign signals of two trans-1,3-butadiene isotopologues that contain a single (13)C isotope and quantify the fragment abundance for the (13)CH3 loss channel for each isotopologue.
我们使用关联旋转取向光谱来揭示丁二烯瞬态离子态中的原子重排。通过研究一个天然样品,我们确定了两种含有单个(13)C同位素的反式-1,3-丁二烯同位素体的信号,并对每个同位素体的(13)CH3损失通道的碎片丰度进行了量化。