Cao Kai, Murshid Nimer, Wang Xiaosong
Department of Chemistry and Waterloo Institute for Nanotechnology (WIN), University of Waterloo, 200 University Ave, Waterloo, ON, N2L 3G1, Canada.
Macromol Rapid Commun. 2015 Apr;36(7):586-96. doi: 10.1002/marc.201400563. Epub 2015 Jan 13.
Synthesis of main-chain metal carbonyl organometallic macromolecules (MCMCOMs) is difficult, mainly due to the instability of metal carbonyl complexes. Despite its challenge a number of MCMCOMs has been prepared by strategically using organometallic, organic, and polymer synthetic chemistry. Main contributions to this research field were reported by the groups of Tyler, Pannell, and Wang and are briefly summarized in this article.
主链羰基金属有机大分子（MCMCOMs）的合成很困难，主要是因为羰基金属配合物不稳定。尽管存在挑战，但通过策略性地运用有机金属、有机和聚合物合成化学，已经制备出了许多MCMCOMs。泰勒、潘内尔和王的研究团队报告了对该研究领域的主要贡献，本文将对这些贡献进行简要总结。
