Food Science and Technology Programme, c/o Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore.
Food Science and Technology Programme, c/o Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore; National University of Singapore (Suzhou) Research Institute, 377 Linquan Street, Suzhou Industrial Park, Jiangsu 215123, People's Republic of China.
Ultrason Sonochem. 2015 Sep;26:399-407. doi: 10.1016/j.ultsonch.2015.01.001. Epub 2015 Jan 13.
Application of high intensity ultrasound has shown potential in the production of Maillard reaction odor-active flavor compounds in model systems. The impact of initial pH, sonication duration, and ultrasound intensity on the production of Maillard reaction products (MRPs) by ultrasound processing in a cysteine-xylose model system were evaluated using Response Surface Methodology (RSM) with a modified mathematical model. Generation of selected MRPs, 2-methylthiophene and tetramethyl pyrazine, was optimal at an initial pH of 6.00, accompanied with 78.1 min of processing at an ultrasound intensity of 19.8 W cm(-2). However, identification of volatiles using gas chromatography-mass spectrometry (GC/MS) revealed that ultrasound-assisted Maillard reactions generated fewer sulfur-containing volatile flavor compounds as compared to conventional heat treatment of the model system. Likely reasons for this difference in flavor profile include the expulsion of H2S due to ultrasonic degassing and inefficient transmission of ultrasonic energy.
高强度超声在模型体系中生成美拉德反应致香风味化合物方面显示出了潜力。本研究采用响应面法(RSM)结合修正数学模型,评估了初始 pH 值、超声持续时间和超声强度对半胱氨酸-木糖模型体系中超声处理生成美拉德反应产物(MRPs)的影响。在初始 pH 值为 6.00 时,采用 19.8 W cm(-2) 的超声强度,处理 78.1 min 可获得最佳的选定 MRPs(2-甲基噻吩和四甲基吡嗪)生成效果。然而,采用气相色谱-质谱联用(GC/MS)对挥发物进行鉴定后发现,与模型体系的常规热处理相比,超声辅助美拉德反应生成的含硫挥发性风味化合物较少。造成这种风味差异的可能原因包括超声脱气导致 H2S 的逸出以及超声能量的传输效率低下。