亲电胺化反应：氮宾的情况
Electrophilic amination: the case of nitrenoids.
作者信息
Starkov Pavel, Jamison Timothy F, Marek Ilan
机构信息
The Mallat Family Laboratory of Organic Chemistry, Schulich Faculty of Chemistry, and The Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, 32000 Haifa (Israel), Fax: (+972) 4-829-3709.
出版信息
Chemistry. 2015 Mar 27;21(14):5278-300. doi: 10.1002/chem.201405779. Epub 2015 Jan 15.
Among the numerous approaches and reagents employed for electrophilic amination, nitrenoids have long stayed out of the limelight. Here, we systematically review the discovery, structural features and chemical reactivity of these promising reagents. We highlight advances in applying the chemistry of nitrenoids as well as outline current limitations and future directions.
在众多用于亲电胺化的方法和试剂中，氮宾长期以来一直未受到关注。在此，我们系统地综述了这些有前景的试剂的发现、结构特征和化学反应性。我们着重介绍了氮宾化学应用方面的进展，并概述了当前的局限性和未来的发展方向。
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