对映体富集的具有圆偏振发光活性的螺旋烯-联吡啶-铼配合物
enantio-Enriched CPL-active helicene-bipyridine-rhenium complexes.
作者信息
Saleh Nidal, Srebro Monika, Reynaldo Thibault, Vanthuyne Nicolas, Toupet Loïc, Chang Victoria Y, Muller Gilles, Williams J A Gareth, Roussel Christian, Autschbach Jochen, Crassous Jeanne
机构信息
Institut des Sciences Chimiques de Rennes, UMR 6226, Institut de Physique de Rennes, UMR 6251, Campus de Beaulieu, CNRS-Université de Rennes 1, 35042 Rennes Cedex, France.
出版信息
Chem Commun (Camb). 2015 Mar 4;51(18):3754-7. doi: 10.1039/c5cc00453e.
Abstract
The incorporation of a rhenium atom within an extended helical π-conjugated bi-pyridine system impacts the chiroptical and photophysical properties of the resulting neutral or cationic complexes, leading to the first examples of rhenium-based phosphors that exhibit circularly polarized luminescence.
摘要
将铼原子引入扩展的螺旋π共轭联吡啶体系会影响所得中性或阳离子配合物的手性光学和光物理性质，从而产生了首例表现出圆偏振发光的铼基磷光体。
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