追求特定结构：首个3-亚氨基氮杂磷环丙烷配合物的合成及其向氧杂磷环丙烷配合物价键异构体的转化。
Going for strain: synthesis of the first 3-imino-azaphosphiridine complexes and their conversion into oxaphosphirane complex valence isomers.
作者信息
Villalba Franco José Manuel, Sasamori Takahiro, Schnakenburg Gregor, Espinosa Ferao Arturo, Streubel Rainer
机构信息
Institut für Anorganische Chemie der Reinischen Friedrich-Wilhelms-Universität Bonn, Gerhard-Domagk-Str.1, 53121 Bonn, Germany.
出版信息
Chem Commun (Camb). 2015 Mar 4;51(18):3878-81. doi: 10.1039/c4cc10266e.
PMID:25655239
Abstract
Reaction of a Li/Cl phosphinidenoid complex with N,N'-dialkyl carbodiimides yielded the novel 3-imino-azaphosphiridine complexes; reaction with water led selectively to the first stable valence isomer of an oxaphosphirane complex.
摘要
锂/氯磷烯配合物与N,N'-二烷基碳二亚胺反应生成了新型的3-亚氨基氮杂磷环丙烷配合物；与水反应则选择性地生成了氧杂磷环丙烷配合物的首个稳定价异构体。
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