激光烧蚀的U原子与(CN)₂的反应：固态氩中UNC、U(NC)₂和U(NC)₄的红外光谱及电子结构计算
Reactions of laser-ablated U atoms with (CN)2: infrared spectra and electronic structure calculations of UNC, U(NC)2, and U(NC)4 in solid argon.
作者信息
Gong Yu, Andrews Lester, Liebov Benjamin K, Fang Zongtang, Garner Edward B, Dixon David A
机构信息
University of Virginia, Department of Chemistry, Charlottesville, VA 22904-4319, USA.
出版信息
Chem Commun (Camb). 2015 Mar 4;51(18):3899-902. doi: 10.1039/c4cc09946j.
PMID:25656733
Abstract
Reactions of laser-ablated U atoms with (CN)2 produce UNC, U(NC)2, and U(NC)4 as the major products, identified from their Ar matrix infrared spectra and precursors partially and fully substituted with (13)C and (15)N. Mixed isotopic multiplets substantiate product stoichiometries. Band positions and quantum chemical calculations verify the isocyanide bonding.
摘要
激光烧蚀的U原子与(CN)₂的反应产生UNC、U(NC)₂和U(NC)₄作为主要产物，这些产物通过它们的氩基质红外光谱以及部分和完全被¹³C和¹⁵N取代的前体得以鉴定。混合同位素多重峰证实了产物的化学计量。谱带位置和量子化学计算验证了异氰化物键合。
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