Wu Xiujuan, Yang Xiaonan, Lee Yong-Min, Nam Wonwoo, Sun Licheng
State Key Laboratory of Fine Chemicals, Dalian University of Technology (DUT), DUT-KTH Joint Education and Research Center on Molecular Devices, Dalian 116024, China.
Chem Commun (Camb). 2015 Mar 7;51(19):4013-6. doi: 10.1039/c4cc10411k.
A nonheme manganese(IV)-oxo complex, Mn(IV)(O)(BQCN), was generated in the photochemical and chemical oxidation of Mn(II)(BQCN) with water as an oxygen source, respectively. The photocatalytic oxidation of organic substrates, such as alcohol and sulfide, by Mn(II)(BQCN) has been demonstrated in both neutral and acidic media.
一种非血红素锰（IV）-氧配合物[Mn(IV)(O)(BQCN)]²⁺分别在以水为氧源对[Mn(II)(BQCN)]²⁺进行光化学氧化和化学氧化的过程中生成。已证明[Mn(II)(BQCN)]²⁺在中性和酸性介质中均可光催化氧化有机底物，如醇和硫化物。
