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无序固体中没有明确的横向声子:硬球玻璃的本质。

Disordered solids without well-defined transverse phonons: the nature of hard-sphere glasses.

机构信息

CAS Key Laboratory of Soft Matter Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale and Department of Physics, University of Science and Technology of China, Hefei 230026, People's Republic of China.

出版信息

Phys Rev Lett. 2015 Jan 23;114(3):035502. doi: 10.1103/PhysRevLett.114.035502.

Abstract

We probe the Ioffe-Regel limits of glasses with repulsions near the zero-temperature jamming transition by calculating the dynamical structure factors. The Ioffe-Regel limit (frequency) is reached when the phonon wavelength is comparable to the mean free path, beyond which phonons are no longer well defined. At zero temperature, the transverse Ioffe-Regel frequency vanishes at the jamming transition with a diverging length, but the longitudinal one does not, which excludes the existence of a diverging length associated with the longitudinal excitations. At low temperatures, the transverse and longitudinal Ioffe-Regel frequencies approach zero at the jamminglike transition and glass transition, respectively. As a consequence, glasses between the glass transition and the jamminglike transition, which are hard-sphere glasses in the low temperature limit, can only carry well-defined longitudinal phonons and have an opposite pressure dependence of the ratio of the shear modulus to the bulk modulus from glasses beyond the jamminglike transition.

摘要

我们通过计算动力学结构因子来探究在接近零温阻塞转变的排斥作用下玻璃的 Ioffe-Regel 极限。当声子波长与平均自由程相当,超过这个范围后,声子就不再能够被明确定义。在零温下,横向 Ioffe-Regel 频率在阻塞转变时随着长度的发散而消失,但纵向的 Ioffe-Regel 频率却不会,这排除了与纵向激发相关的发散长度的存在。在低温下,横向和纵向的 Ioffe-Regel 频率分别在类似阻塞的转变和玻璃化转变处趋近于零。因此,在玻璃化转变和类似阻塞的转变之间的玻璃,在低温极限下是硬球玻璃,只能携带明确定义的纵向声子,并且与类似阻塞的转变之后的玻璃相比,剪切模量与体积模量之比的压力依赖性相反。

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