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铰接棒 - 一类基于寡螺环缩酮 (OSK) 的新型分子棒。

Articulated rods - a novel class of molecular rods based on oligospiroketals (OSK).

机构信息

Institut für Chemie, Universität Potsdam, Karl-Liebknecht-Str. 24-25, D-14476 Potsdam, Germany.

Institut für Biologie/Molekulare Biophysik, Humboldt Universität zu Berlin, Invalidenstr. 42, D-10115 Berlin, Germany.

出版信息

Beilstein J Org Chem. 2015 Jan 16;11:74-84. doi: 10.3762/bjoc.11.11. eCollection 2015.

DOI:10.3762/bjoc.11.11
PMID:25670995
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4311589/
Abstract

We developed a new type of molecular rods consisting of two (or more) rigid units linked by a flexible joint. Consequently we called these constructs articulated rods (ARs). The syntheses of ARs were carried out by a flexible and modular approach providing access to a number of compounds with various functionalizations in terminal positions. First applications were presented with pyrene, cinnamoyl and anthracenyl labelled ARs.

摘要

我们开发了一种由两个（或更多）刚性单元通过柔性连接键连接而成的新型分子棒。因此，我们将这些构建体称为铰接分子棒（AR）。通过灵活的模块化方法进行 AR 的合成，可获得一系列在末端位置具有各种官能团的化合物。首先介绍了带有芘、肉桂酰基和蒽基标记的 AR 的应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f50a/4311589/c8d5d6d062f4/Beilstein_J_Org_Chem-11-74-g009.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f50a/4311589/d35d980f94de/Beilstein_J_Org_Chem-11-74-g011.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f50a/4311589/31ed9a5fbd8f/Beilstein_J_Org_Chem-11-74-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f50a/4311589/91ed9131e32a/Beilstein_J_Org_Chem-11-74-g019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f50a/4311589/547008a90285/Beilstein_J_Org_Chem-11-74-g020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f50a/4311589/1353f29943e2/Beilstein_J_Org_Chem-11-74-g005.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f50a/4311589/2ed7f11f16d2/Beilstein_J_Org_Chem-11-74-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f50a/4311589/f4e11389c702/Beilstein_J_Org_Chem-11-74-g021.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f50a/4311589/c8d5d6d062f4/Beilstein_J_Org_Chem-11-74-g009.jpg

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