来自大环亚胺动态组合库的自发结晶过程中的镜像对称性破缺。
Mirror symmetry breaking upon spontaneous crystallization from a dynamic combinatorial library of macrocyclic imines.
作者信息
Ziach Krzysztof, Jurczak Janusz
机构信息
Faculty of Chemistry, University of Warsaw, Pasteura 1, 02-093 Warsaw, Poland.
出版信息
Chem Commun (Camb). 2015 Mar 11;51(20):4306-9. doi: 10.1039/c4cc10083b.
PMID:25673282
Abstract
Spontaneous emergence of solid state chirality and mirror symmetry breaking occurred upon crystallization from a small templated dynamic combinatorial library (DCL) of achiral macrocyclic imines, and depended strongly on the nature of library building blocks (amines, aldehydes, template cations and anions) and crystallization temperature.
摘要
在手性大环亚胺的小型模板动态组合库（DCL）结晶过程中，固态手性和镜像对称性破缺自发出现，且强烈依赖于库构建单元（胺、醛、模板阳离子和阴离子）的性质以及结晶温度。
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