State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.
Chem Commun (Camb). 2015 Mar 14;51(21):4465-8. doi: 10.1039/c4cc10292d.
Substitution-inert, redox- and photo-active ruthenium(II) complexes based on 2,2',6',2''-terpyridine ligands were self-assembled into discrete supramolecular cages via coordination to palladium(II) centres and characterised by NMR, ESI-MS and X-ray crystallography.
基于 2,2',6',2''-三联吡啶配体的取代惰性、氧化还原和光活性钌(II)配合物通过与钯(II)中心配位自组装成离散的超分子笼,并通过 NMR、ESI-MS 和 X 射线晶体学进行了表征。