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三(4-吗啉-8-羟基喹啉)铝的合成与光物理性质。

Synthesis and photophysical properties of aluminium tris-(4-morpholine-8-hydroxyquinoline).

机构信息

Department of Science and Mathematics, Faculty of Petroleum and Mining Engineering, Suez Canal University, Suez 43721, Egypt.

出版信息

J Adv Res. 2013 Nov;4(6):525-9. doi: 10.1016/j.jare.2012.09.003. Epub 2012 Oct 25.

Abstract

Aluminium tris(4-morpholinyl-8-hydroxyquinoline) has been synthesized and characterized. The photoluminescence measurements showed that the new derivative is blue shifted and has relative photoluminescence quantum yield two times higher compared to the pristine Al tris(8-hydroxyquinoline). Deferential scanning colorimetric studies revealed that the newly synthesized Alq3 derivative in this work is amorphous material with the highest transition glass temperature value among the reported amorphous Alq3 derivatives.

摘要

三(4-吗啉基-8-羟基喹啉)铝已被合成并进行了表征。光致发光测量表明,与原始的 Al 三(8-羟基喹啉)相比,新衍生物发生了蓝移,且具有相对光致发光量子产率高两倍。差示扫描量热研究表明,本工作中合成的 Alq3 衍生物是无定形材料,其最高转变玻璃化温度值在已报道的无定形 Alq3 衍生物中最高。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6630/4294783/26474106c85e/gr1.jpg

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