Song Lei, Zhang Bin, Deng Wen
Huan Jing Ke Xue. 2014 Oct;35(10):3674-82.
The effects of pore structure, graphite and surface structure of waste tea activated carbon on its desulfurization and denitrification performance were investigated. The adsorption kinetics and adsorption process were also studied. The results showed that less graphitization, lower micropore size and more nitrogenous basic group of adsorbent enhanced its desulfurization ability. When well- developed mesopores were present in adsorbent, the NO removal efficiency was decreased, while more nitrogenous basic groups promoted the removal rate of NO. When SO2 and NO were removed together, competing adsorption occurred. After oxygen and steam were introduced to the flue gas, the removal efficiencies of SO2 and NO were increased. The adsorption of SO2 and NO onto waste tea activated carbon was physical adsorption without O2 and H2O, while the vapor promoted chemical adsorption of SO2 in the presence of water and oxygen. The adsorption process of the material can be well described by Bangham's kinetic equation, and the value of R2 was no less than 0.989. O2 and water vapor slowed the adsorption rates of SO2 and NO.
研究了废茶活性炭的孔隙结构、石墨化程度和表面结构对其脱硫脱硝性能的影响。同时还研究了吸附动力学和吸附过程。结果表明,吸附剂的石墨化程度较低、微孔尺寸较小和含氮碱性基团较多可提高其脱硫能力。当吸附剂中存在发达的中孔时,NO的去除效率降低,而较多的含氮碱性基团促进了NO的去除率。当同时去除SO2和NO时,会发生竞争吸附。向烟气中引入氧气和水蒸气后,SO2和NO的去除效率提高。在没有O2和H2O的情况下,SO2和NO在废茶活性炭上的吸附为物理吸附,而在有水和氧气存在的情况下,水蒸气促进了SO2的化学吸附。该材料的吸附过程可用Bangham动力学方程很好地描述,R2值不小于0.989。O2和水蒸气减缓了SO2和NO的吸附速率。