Gole Bappaditya, Sanyal Udishnu, Mukherjee Partha Sarathi
Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore, India.
Chem Commun (Camb). 2015 Mar 21;51(23):4872-5. doi: 10.1039/c4cc09228g.
The problem associated with metal nanoparticle (NP) agglomeration when trying to achieve a high loading amount has been solved by a new method of functionalization of MOFs' pores with terminal alkyne moieties. The alkynophilicity of the Au(3+) ions has been utilized successfully for an exceptionally high loading (∼50 wt%) of Au-NPs on supported functionalized MOFs.
通过一种用末端炔基部分对金属有机框架（MOF）孔进行功能化的新方法，解决了在试图实现高负载量时与金属纳米颗粒（NP）团聚相关的问题。Au(3+)离子的亲炔性已成功用于在负载型功能化MOF上实现异常高的金纳米颗粒负载量（约50重量%）。
