二氧代双（戊烷 - 2,4 - 二酮 - κ(2) O,O'）[1 - 苯基 - 3 - （吡啶 - 4 - 基）丙烷 - κN]铀（VI）的晶体结构
Crystal structure of dioxidobis(pentane-2,4-dionato-κ(2) O,O')[1-phenyl-3-(pyridin-4-yl)propane-κN]uranium(VI).
作者信息
Kawasaki Takeshi, Kitazawa Takafumi
机构信息
Department of Chemistry, Faculty of Science, Toho University, 2-2-1 Miyama, Funabashi, Chiba 274-8510, Japan.
Department of Chemistry, Faculty of Science, Toho University, 2-2-1 Miyama, Funabashi, Chiba 274-8510, Japan ; Research Center for Materials with Integrated Properties, Toho University, Miyama, Funabashi, Chiba 274-8510, Japan.
出版信息
Acta Crystallogr E Crystallogr Commun. 2015 Jan 1;71(Pt 1):42-4. doi: 10.1107/S2056989014026607.
In the title compound, [UO2(C5H7O2)2(C14H15N)], the uran-yl(VI) unit (O=U=O) is coordinated to two acetyl-acetonate (acac) anions and one 1-phenyl-3-(pyridin-4-yl)propane (ppp) mol-ecule. The geometry around the U atom is UNO6 penta-gonal-bipyramidal; two uran-yl(VI) O atoms are located at the axial positions, whereas four O atoms from two chelating bidentate acac ligands and one N atom of a ppp ligand form the equatorial plane.
在标题化合物[UO₂(C₅H₇O₂)₂(C₁₄H₁₅N)]中，铀酰(VI)单元(O=U=O)与两个乙酰丙酮(acac)阴离子和一个1-苯基-3-(吡啶-4-基)丙烷(ppp)分子配位。U原子周围的几何构型为UNO₆五角双锥；两个铀酰(VI) O原子位于轴向位置，而来自两个螯合双齿acac配体的四个O原子和一个ppp配体的N原子形成赤道平面。
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