锰-萨伦催化苄基C-H活化用于合成含芳基[(18)F]CF3的正电子发射断层扫描（PET）探针。
Mn-salen catalysed benzylic C-H activation for the synthesis of aryl [(18)F]CF3-containing PET probes.
作者信息
Carroll L, Evans H L, Spivey A C, Aboagye E O
机构信息
Comprehensive Cancer Imaging Centre, Department of Surgery and Cancer, Imperial College London, Hammersmith Campus, Du Cane Road, London, W12 0NN, UK.
出版信息
Chem Commun (Camb). 2015 May 18;51(40):8439-41. doi: 10.1039/c4cc05762g.
PMID:25714781
Abstract
The development of a Mn-salen complex catalysed oxidative benzylic fluorination of non-activated C-H bonds using [(18)F]fluoride is described for installation of [(18)F]CHRF, [(18)F]CR2F and particularly [(18)F]CF3 containing groups in the presence of other functional groups.
摘要
描述了一种锰-萨伦配合物催化的使用[（18）F]氟化物对未活化的C-H键进行氧化苄基氟化反应，用于在其他官能团存在的情况下引入含[（18）F]CHRF、[（18）F]CR2F特别是[（18）F]CF3的基团。
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