通过氧鎓盐对烯丙基醚进行氧化裂解
Oxidative cleavage of allyl ethers by an oxoammonium salt.
作者信息
Kelly Christopher B, Ovian John M, Cywar Robin M, Gosselin Taylor R, Wiles Rebecca J, Leadbeater Nicholas E
机构信息
Department of Chemistry, University of Connecticut, 55 North Eagleville Road, Storrs, CT 06269, USA.
出版信息
Org Biomol Chem. 2015 Apr 14;13(14):4255-9. doi: 10.1039/c5ob00270b. Epub 2015 Mar 6.
PMID:25748071
Abstract
A method to oxidatively cleave allyl ethers to their corresponding aldehydes mediated by an oxoammonium salt is described. Using a biphasic solvent system and mild heating, cleavage proceeds readily, furnishing a variety of α,β-unsaturated aldehydes and ketones.
摘要
描述了一种由氧鎓盐介导将烯丙基醚氧化裂解为相应醛的方法。使用双相溶剂体系并温和加热，裂解反应很容易进行，可得到多种α,β-不饱和醛和酮。
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