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一种通过分子间卤素-氢相互作用具有聚集诱导发光特性的溴代菲并咪唑衍生物。

A Br-substituted phenanthroimidazole derivative with aggregation induced emission from intermolecular halogen-hydrogen interactions.

作者信息

Zhang Ying, Wang Jun-Hao, Zheng Ji, Li Dan

机构信息

Department of Chemistry, School of Life Science and Technology, Jinan University, Guangzhou 510632, China.

出版信息

Chem Commun (Camb). 2015 Apr 14;51(29):6350-3. doi: 10.1039/c5cc00490j.

DOI:10.1039/c5cc00490j
PMID:25761827
Abstract

A unique aggregation induced emission (AIE) active emitter based on a Br-substituted phenanthroimidazole derivative was reported. The yellowish green emission with high quantum yield and a large Stokes shift (∼150 nm) in the aggregated state is proposed to be obtained from weak interactions especially C-H···Br interactions.

摘要

报道了一种基于溴取代菲并咪唑衍生物的独特的聚集诱导发光(AIE)活性发光体。据推测,在聚集态下具有高量子产率和大斯托克斯位移(约150 nm)的黄绿色发射是由弱相互作用特别是C-H···Br相互作用产生的。

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