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尿素酒石酸单晶的结构、光学、热学和力学性能

Structural, optical, thermal and mechanical properties of Urea tartaric acid single crystals.

作者信息

Vinothkumar P, Rajeswari K, Kumar R Mohan, Bhaskaran A

机构信息

Department of Physics, Presidency College, Chennai 600 005, India.

Department of Physics, Presidency College, Chennai 600 005, India.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2015 Jun 15;145:33-39. doi: 10.1016/j.saa.2015.02.063. Epub 2015 Feb 27.

Abstract

Urea tartaric acid (UT) an organic nonlinear optical (NLO) material was synthesized from aqueous solution and the crystals were grown by the slow evaporation technique. The single crystal X-ray diffraction (XRD) analysis revealed that the UT crystal belongs to the orthorhombic system. The functional groups of UT have been identified by the Fourier transform infrared spectral studies. The optical transparent window in the visible and near the IR regions was investigated. The transmittance of UT has been used to calculate the refractive index (n) as a function of the wavelength. The nonlinear optical property of the grown crystal has been confirmed by the Kurtz powder second harmonic generation test. The birefringence of the crystal was determined using a tungsten halogen lamp source. The laser induced surface damage threshold for the grown crystal was measured using the Nd:YAG laser. The anisotropic in mechanical property of the grown crystals was studied using Vicker's microhardness tester at different planes. The etch pit density of UT crystals was investigated. The thermal behavior of UT was investigated using the TG-DTA and DSC studies.

摘要

酒石酸尿素(UT)是一种有机非线性光学(NLO)材料,通过水溶液合成,并采用缓慢蒸发技术生长晶体。单晶X射线衍射(XRD)分析表明,UT晶体属于正交晶系。通过傅里叶变换红外光谱研究确定了UT的官能团。研究了可见光和近红外区域的光学透明窗口。UT的透过率已被用于计算作为波长函数的折射率(n)。通过库尔兹粉末二次谐波产生测试证实了生长晶体的非线性光学性质。使用钨卤素灯源测定晶体的双折射。使用Nd:YAG激光测量生长晶体的激光诱导表面损伤阈值。在不同平面上使用维氏显微硬度测试仪研究了生长晶体的力学性能各向异性。研究了UT晶体的蚀刻坑密度。使用TG-DTA和DSC研究了UT的热行为。

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