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涨落耗散定理与过冷液体中的介电响应。

Fluctuation-dissipation theorem and the dielectric response in supercooled liquids.

作者信息

Kondrin M V, Brazhkin V V, Lebed Y B

机构信息

Institute for High Pressure Physics RAS, 142190 Troitsk, Moscow, Russia.

Institute for Nuclear Research RAS, 142190 Troitsk, Moscow, Russia.

出版信息

J Chem Phys. 2015 Mar 14;142(10):104505. doi: 10.1063/1.4914185.

Abstract

We consider the correlation between static conductivity and dynamic dielectric relaxation in a number of polar organic liquids. Experimental evidence suggests that in the simple cases the linear dependence between characteristic frequency of relaxation process and the value of static susceptibility is observed. However, this proportionality can be broken due to the appearance of additional relaxation processes (secondary or high-frequency ones) so it can be confused with the "fractional" variant of Debye-Stokes-Einstein relation.

摘要

我们研究了多种极性有机液体中静态电导率与动态介电弛豫之间的相关性。实验证据表明,在简单情况下,会观察到弛豫过程的特征频率与静态磁化率值之间存在线性关系。然而,由于额外弛豫过程(次级或高频过程)的出现,这种比例关系可能会被打破,因此它可能会与德拜 - 斯托克斯 - 爱因斯坦关系的“分数”变体相混淆。

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