Sun Yu, Li Xiaopeng, Caravella Alessio, Gao Rongke
School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing (USTB), Xueyuan Road 30, Beijing, 100083 (P. R. China).
Chemistry. 2015 Apr 27;21(18):6682-5. doi: 10.1002/chem.201406532. Epub 2015 Mar 17.
Herein, nanorod structures and four-leaf clover structures of fluorescent zinc 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine (ZnTPyP)-containing coordination polymer particles (CPPs) were first synthesized by a bottom-up strategy assisted by surfactants and then employed as seed structures for further shape-transformation reactions. We have successfully designed the morphological transformation for different dimensions, achieving the controlled formation of octahedron structures at both the nanometer scale and micrometer scale from the seed structures. Our approach illustrates a new method to design and synthesize metalloporphyrin-containing CPPs in a systematic and controllable manner.
在此，首先通过表面活性剂辅助的自下而上策略合成了含荧光锌5,10,15,20-四(4-吡啶基)-21H,23H-卟啉(ZnTPyP)的配位聚合物颗粒(CPPs)的纳米棒结构和四叶草结构，然后将其用作进一步形状转变反应的种子结构。我们成功地设计了不同维度的形态转变，实现了从种子结构在纳米尺度和微米尺度上可控地形成八面体结构。我们的方法展示了一种以系统且可控的方式设计和合成含金属卟啉CPPs的新方法。
