Magnani N, Caciuffo R, Wilhelm F, Colineau E, Eloirdi R, Griveau J-C, Rusz J, Oppeneer P M, Rogalev A, Lander G H
European Commission, Joint Research Centre (JRC), Institute for Transuranium Elements (ITU), Postfach 2340, D-76125 Karlsruhe, Germany.
European Synchrotron Radiation Facility (ESRF), Boîte Postale 220, F-38043 Grenoble, France.
Phys Rev Lett. 2015 Mar 6;114(9):097203. doi: 10.1103/PhysRevLett.114.097203.
Trivalent americium has a nonmagnetic (J=0) ground state arising from the cancellation of the orbital and spin moments. However, magnetism can be induced by a large molecular field if Am^{3+} is embedded in a ferromagnetic matrix. Using the technique of x-ray magnetic circular dichroism, we show that this is the case in AmFe_{2}. Since ⟨J_{z}⟩=0, the spin component is exactly twice as large as the orbital one, the total Am moment is opposite to that of Fe, and the magnetic dipole operator ⟨T_{z}⟩ can be determined directly; we discuss the progression of the latter across the actinide series.
三价镅具有非磁性(J = 0)基态,这是由轨道矩和自旋矩的抵消产生的。然而,如果将Am³⁺嵌入铁磁基体中,大的分子场可以诱导出磁性。利用X射线磁圆二色性技术,我们表明在AmFe₂中就是这种情况。由于〈Jz〉= 0,自旋分量正好是轨道分量的两倍,镅的总磁矩与铁的磁矩相反,并且磁偶极算符〈Tz〉可以直接确定;我们讨论了后者在锕系元素中的变化情况。