College of Environmental & Resource Science, Zhejiang University, Hangzhou, 310058, China,
Environ Sci Pollut Res Int. 2015 Aug;22(15):11314-26. doi: 10.1007/s11356-015-4377-y. Epub 2015 Mar 25.
Legacy nitrogen (N) sources originating from anthropogenic N inputs (NANI) may be a major cause of increasing riverine N exports in many regions, despite a significant decline in NANI. However, little quantitative knowledge exists concerning the lag effect of NANI on riverine N export. As a result, the N leaching lag effect is not well represented in most current watershed models. This study developed a lagged variable model (LVM) to address temporally dynamic export of watershed NANI to rivers. Employing a Koyck transformation approach used in economic analyses, the LVM expresses the indefinite number of lag terms from previous years' NANI with a lag term that incorporates the previous year's riverine N flux, enabling us to inversely calibrate model parameters from measurable variables using Bayesian statistics. Applying the LVM to the upper Jiaojiang watershed in eastern China for 1980-2010 indicated that 97% of riverine export of annual NANI occurred in the current year and succeeding 10 years (11 years lag time) and ~72% of annual riverine N flux was derived from previous years' NANI. Existing NANI over the 1993-2010 period would have required a 22% reduction to attain the target TN level (1.0 mg N L(-1)), guiding watershed N source controls considering the lag effect. The LVM was developed with parsimony of model structure and parameters (only four parameters in this study); thus, it is easy to develop and apply in other watersheds. The LVM provides a simple and effective tool for quantifying the lag effect of anthropogenic N input on riverine export in support of efficient development and evaluation of watershed N control strategies.
传统氮(N)源源自人为氮输入(NANI),尽管 NANI 显著减少,但可能仍是许多地区河流 N 输出增加的主要原因。然而,关于 NANI 对河流 N 输出的滞后效应,定量知识很少。因此,在大多数当前的流域模型中,N 淋溶滞后效应并未得到很好的体现。本研究开发了滞后变量模型(LVM)来解决流域 NANI 向河流的时间动态输出问题。该模型采用经济分析中使用的 Koyck 变换方法,用包含前一年河流 N 通量的滞后项来表示前几年 NANI 的不定数量的滞后项,使我们能够使用贝叶斯统计从可测量变量中反向校准模型参数。将 LVM 应用于中国东部的椒江上游流域 1980-2010 年的数据表明,97%的年度 NANI 河流输出发生在当年及随后的 10 年(11 年的滞后时间),~72%的年度河流 N 通量来自前几年的 NANI。如果要达到目标 TN 水平(1.0 mg N L(-1)),就需要在 1993-2010 年期间减少 22%的现有 NANI,这为考虑滞后效应的流域 N 源控制提供了指导。该 LVM 的模型结构和参数非常简洁(本研究仅使用四个参数),因此易于在其他流域开发和应用。LVM 为量化人为氮输入对河流输出的滞后效应提供了一种简单有效的工具,支持流域氮控制策略的有效开发和评估。