锂硼基在低氧化态第15族元素化学中作为还原剂的应用：氨基二锑烯和硼基二铋烯的合成与表征
Utilisation of a lithium boryl as a reducing agent in low oxidation state group 15 chemistry: synthesis and characterisation of an amido-distibene and a boryl-dibismuthene.
作者信息
Dange Deepak, Davey Amelia, Abdalla Joseph A B, Aldridge Simon, Jones Cameron
机构信息
School of Chemistry, P.O. Box 23, Monash University, Melbourne, VIC 3800, Australia.
出版信息
Chem Commun (Camb). 2015 Apr 28;51(33):7128-31. doi: 10.1039/c5cc01772f.
The first examples of an amido-distibene, L(†)Sb[double bond, length as m-dash]SbL(†) (L(†) = -N(Ar(†))(SiPr(i)3), Ar(†) = C6H2{C(H)Ph2}2Pr(i)-2,6,4), and a boryl dibismuthene, {(DAB)B}Bi[double bond, length as m-dash]Bi{B(DAB)} (DAB = {(C6H3Pr(i)2-2,6)NCH}2, have been prepared by reaction of a lithium boryl complex, (THF)2LiB(DAB), with extremely bulky amido-group 15 dihalide precursor compounds. In these reactions, the lithium boryl acts as a boryl transfer reagent and/or a strong reducing agent.
首例氨基二锑烯L(†)Sb[双键，长度为m破折号]SbL(†)（L(†) = -N(Ar(†))(SiPr(i)3)，Ar(†) = C6H2{C(H)Ph2}2Pr(i)-2,6,4）和硼基二铋烯{(DAB)B}Bi[双键，长度为m破折号]Bi{B(DAB)}（DAB = {(C6H3Pr(i)2-2,6)NCH}2）已通过锂硼基配合物(THF)2LiB(DAB)与极其庞大的氨基第15族二卤化物前体化合物反应制备而成。在这些反应中，锂硼基充当硼基转移试剂和/或强还原剂。
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