School of Chemistry, PO Box 23, Monash University, Melbourne, VIC 3800, Australia.
Chem Commun (Camb). 2014 Mar 4;50(18):2321-3. doi: 10.1039/c3cc49651a. Epub 2014 Jan 21.
The first amido-distannyne, L(†)SnSnL(†) (L(†) = -N(Ar(†))(SiPr(i)3), Ar(†) = C6H2{C(H)Ph2}2Pr(i)-2,6,4), has been prepared and shown to possess a very long Sn-Sn single bond; the compound activates dihydrogen under ambient conditions to give L(†)Sn(μ-H)2SnL(†), and reacts with Bu(t)NC to give a stable adduct complex, L(†)(Bu(t)NC)SnSn(CNBu(t))L(†).
首例酰胺二芳基二锡烷，L(†)SnSnL(†)（L(†) = -N(Ar(†))(SiPr(i)3)，Ar(†) = C6H2{C(H)Ph2}2Pr(i)-2,6,4），已被制备并证实具有非常长的 Sn-Sn 单键；该化合物在环境条件下激活氢气得到 L(†)Sn(μ-H)2SnL(†)，并与 Bu(t)NC 反应得到稳定的加合物络合物 L(†)(Bu(t)NC)SnSn(CNBu(t))L(†)。
