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含高氮量的基于3,6-二硝基吡唑并[4,3-c]吡唑的高能共晶体的奇特案例:一种替代盐形成的方法。

Curious cases of 3,6-dinitropyrazolo[4,3-c]pyrazole-based energetic cocrystals with high nitrogen content: an alternative to salt formation.

作者信息

Zhang Jiaheng, Parrish Damon A, Shreeve Jean'ne M

机构信息

Department of Chemistry, University of Idaho, Moscow, Idaho 83844-2343, USA.

出版信息

Chem Commun (Camb). 2015 Apr 30;51(34):7337-40. doi: 10.1039/c5cc01745a.

DOI:10.1039/c5cc01745a
PMID:25820478
Abstract

Two structurally interesting 3,6-dinitropyrazolo[4,3-c]pyrazole-based energetic cocrystals were prepared and confirmed by single crystal X-ray diffraction. As novel energetic materials, these two unusual neutral acid-base complexes possess high nitrogen content, good detonation properties, and improved impact and friction sensitivities which highlight their potential energetic applications.

摘要

制备了两种结构有趣的基于3,6-二硝基吡唑并[4,3-c]吡唑的含能共晶体,并通过单晶X射线衍射进行了确认。作为新型含能材料,这两种不同寻常的中性酸碱配合物具有高氮含量、良好的爆轰性能以及改善的撞击和摩擦感度,这些特性突出了它们潜在的含能应用价值。

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