蓝藻素的碳类似物的合成。

Synthesis of a carbon analogue of scytonemin.

作者信息

Mukai Chisato, Arima Katsuya, Hirata Shuichi, Yasuda Shigeo

机构信息

Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University.

出版信息

Chem Pharm Bull (Tokyo). 2015;63(4):273-7. doi: 10.1248/cpb.c14-00838.

DOI:10.1248/cpb.c14-00838

PMID:25832021

Abstract

The synthesis of a carbon analogue of scytonemin was accomplished on the basis of molybdenum-mediated intramolecular double Pauson-Khand type reaction of bis(allenyne), followed by the double aldol condensation of the formed double Pauson-Khand type adduct.

摘要

基于钼介导的双（丙二烯炔）分子内双Pauson-Khand型反应，随后对形成的双Pauson-Khand型加合物进行双羟醛缩合反应，完成了scytonemin碳类似物的合成。