外消旋-3-羟基-2-（对甲苯基）-2,3,3a,4,7,7a-六氢-1H-4,7-亚甲基异吲哚-1-酮的晶体结构
Crystal structure of rac-3-hy-droxy-2-(p-tol-yl)-2,3,3a,4,7,7a-hexa-hydro-1H-4,7-methano-isoindol-1-one.
作者信息
Aslantaş Mehmet, Çelik Cumali, Çelik Ömer, Karayel Arzu
机构信息
Department of Physics, Faculty of Sciences and Arts, University of Kahramanmaras Sutcuimam, Avsar Campus 46100, Kahramanmaras, Turkey.
Yalova Community Collage, University of Yalova, 77200 Yalova, Turkey.
出版信息
Acta Crystallogr E Crystallogr Commun. 2015 Feb 4;71(Pt 3):o143-4. doi: 10.1107/S2056989015001942. eCollection 2015 Mar 1.
In the title compound, C16H17NO2, the cyclo-hexene ring adopts a boat conformation, and the five-membered rings have envelope conformations with the bridging atom as the flap. Their mean planes are oriented at a dihedral angle of 86.51 (7)°. The mol-ecular structure is stabilized by a short intra-molecular C-H⋯O contact. In the crystal, mol-ecules are linked by O-H⋯O hydrogen bonds forming chains propagating along [100]. The chains are linked by C-H⋯π inter-actions, forming slabs parallel to (001).
在标题化合物C₁₆H₁₇NO₂中，环己烯环呈船式构象，五元环呈信封式构象，桥连原子为翼片。它们的平均平面以86.51 (7)°的二面角取向。分子结构通过短程分子内C—H⋯O接触得以稳定。在晶体中，分子通过O—H⋯O氢键相连形成沿[100]方向延伸的链。这些链通过C—H⋯π相互作用相连，形成平行于(001)的片层。
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