S-己基（E）-3-（4-甲氧基-亚苄基）二硫代氨基脲的晶体结构
Crystal structure of S-hexyl (E)-3-(4-methoxy-benzyl-idene)di-thio-carbazate.
作者信息
Begum M S, Howlader M B H, Miyatake R, Zangrando E, Sheikh M C
机构信息
Department of Chemistry, Rajshahi University, Rajshahi-6205, Bangladesh.
Center for Environmental Conservation and Research Safety, University of Toyama, 3190 Gofuku, Toyama 930-8555, Japan.
出版信息
Acta Crystallogr E Crystallogr Commun. 2015 Feb 25;71(Pt 3):o199. doi: 10.1107/S2056989015003199. eCollection 2015 Mar 1.
In the title compound, C15H22N2OS2, the di-thio-carbazate group adopts an EE conformation with respect to the C=N bond of the benzyl-idene moiety. The hexyl side chain adopts an extended conformation and the C-S-C-C torsion angle is -93.36 (13)°. In the crystal, inversion dimers linked by pairs of N-H⋯S hydrogen bonds generate R 2 (2)(8) loops.
在标题化合物C₁₅H₂₂N₂OS₂中，二硫代卡巴腙基团相对于亚苄基部分的C=N键采取EE构象。己基侧链采取伸展构象，C-S-C-C扭转角为-93.36 (13)°。在晶体中，通过N-H⋯S氢键对连接的反演二聚体形成R₂²(8)环。
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