State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032 (China).
Angew Chem Int Ed Engl. 2015 May 18;54(21):6265-9. doi: 10.1002/anie.201500201. Epub 2015 Apr 2.
A palladium-catalyzed enantioselective C-H arylation of N-(o-bromoaryl)-diarylphosphinic amides is described for the synthesis of phosphorus compounds bearing a P-stereogenic center. The method provides good enantioselectivities and high yields. The products were readily transformed into P-chiral biphenyl monophosphine ligands.
钯催化的 N-(邻溴芳基)-二芳基膦酰胺的对映选择性 C-H 芳基化反应，用于合成具有 P-手性中心的磷化合物。该方法提供了良好的对映选择性和收率。产物可容易地转化为 P-手性联苯单膦配体。
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