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使用一维光子晶体实现显色指数接近 100 的高效半透明聚合物太阳能电池。

Highly efficient semitransparent polymer solar cells with color rendering index approaching 100 using one-dimensional photonic crystal.

机构信息

†State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, 2699 Qianjin Street, Changchun 130012, People's Republic of China.

‡School of Applied Physics and Materials, Institute of Thin Film and Nanomaterials, WuYi University, No. 22 Dongchen Cun, Jiangmen 529020, People's Republic of China.

出版信息

ACS Appl Mater Interfaces. 2015 May 13;7(18):9920-8. doi: 10.1021/acsami.5b02039. Epub 2015 Apr 23.

Abstract

Window application is the important aim for semitransparent solar cells (STPSC) investigation. Here, we demonstrate a method to achieve significantly improved color rendering index (CRI), depressed chromaticity difference (DC), and enhanced power conversion efficiency (PCE) simultaneously by introducing the one-dimensional photonic crystals (1DPCs) Bragg reflector structure onto the STPSC. The device performance is studied from aspects of color perception, electrical properties, and theoretical optical simulations. The STPSCs exhibit achromatic transparency nature color perceptions, especially for the STPSCs with 1DPCs (pairs ≥ 3) under AM 1.5G illumination light source, standard illuminant D65, and standard illuminant A. The excellent CRI is approaching 97 with lower DC about 0.0013 for the device with 5 pairs of 1DPC illumined by AM 1.5G illumination light source. At the same time, the PCE of STPSC devices with 5 pairs of 1DPC was improved from 4.87 ± 0.14% to 5.31 ± 0.13% compared to without. This method provides a facilitative approach to realizing excellent SPTSC window application.

摘要

窗口应用是研究半透明太阳能电池(STPSC)的重要目标。在这里,我们展示了一种方法,通过在 STPSC 上引入一维光子晶体(1DPC)布拉格反射器结构,同时显著提高显色指数(CRI)、降低色度差(DC)和增强功率转换效率(PCE)。从颜色感知、电气性能和理论光学模拟等方面研究了器件性能。STPSCs 呈现出非彩色透明的自然颜色感知,特别是在 AM 1.5G 照明光源、标准照明体 D65 和标准照明体 A 照明下,具有 1DPC(对≥3)的 STPSCs。在 AM 1.5G 照明光源照射下,具有 5 对 1DPC 的器件的优异 CRI 接近 97,DC 约为 0.0013。同时,与没有 1DPC 的器件相比,具有 5 对 1DPC 的 STPSC 器件的 PCE 从 4.87±0.14%提高到 5.31±0.13%。该方法为实现优异的 SPTSC 窗口应用提供了一种便利的途径。

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