Department of Chemistry and MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago, P.O. Box 56, Dunedin, New Zealand.
Chem Soc Rev. 2015 May 21;44(10):2880-92. doi: 10.1039/c4cs00376d. Epub 2015 Apr 24.
The observation of spin crossover with thermal hysteresis loops of more than a few Kelvin remains relatively uncommon and unpredictable, so is a relatively underdeveloped, but important, area of spin crossover, particularly for memory applications. Lessons learnt regarding the origins, and the practicalities of the proper study and reporting, of thermal hysteresis loops are considered and explained, from a synthetic chemists perspective, after a general introduction to the field of spin crossover.
具有数开尔文以上热滞回线的自旋交叉的观察仍然相对罕见且不可预测，因此它是自旋交叉的一个相对欠发达但重要的领域，特别是对于记忆应用。在介绍自旋交叉领域的一般情况后，从合成化学家的角度出发，考虑并解释了热滞回线的起源以及正确研究和报告的实际情况。
