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超薄氧化铜纳米棒:苯乙烯环氧化反应中的可控合成及优异催化性能

Ultrathin CuO nanorods: controllable synthesis and superior catalytic properties in styrene epoxidation.

作者信息

Jia Wei, Liu Yuxi, Hu Pengfei, Yu Rong, Wang Yu, Ma Lei, Wang Dingsheng, Li Yadong

机构信息

Department of Chemistry and Collaborative Innovation Center for Nanomaterial Science and Engineering, Tsinghua University, Beijing 100084, P. R. China.

出版信息

Chem Commun (Camb). 2015 May 25;51(42):8817-20. doi: 10.1039/c5cc02480c.

DOI:10.1039/c5cc02480c
PMID:25920405
Abstract

Ultrathin copper oxide (CuO) nanorods with diameters of ∼3.6 nm were obtained in one step using oleylamine (OAm) as both the solvent and the surface controller. The oriented attachment is responsible for the formation of the ultrathin CuO nanorods. Furthermore, this ultrathin nanostructure catalyst exhibited excellent activity and high styrene oxide yields in styrene epoxidation.

摘要

以油胺(OAm)作为溶剂和表面控制剂,一步法制备出了直径约为3.6 nm的超薄氧化铜(CuO)纳米棒。超薄CuO纳米棒的形成归因于定向附着。此外,这种超薄纳米结构催化剂在苯乙烯环氧化反应中表现出优异的活性和高环氧苯乙烷产率。

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